physical chemistry
$$ce{Pb^4+ + 2 e+ <=> Pb^2+}$$ For a classical lead–acid battery, the overall cell reaction is approximately $$ce{Pb + PbO2 + 2H+ + 2 HSO4- <=> 2 PbSO4 + 2 H2O}$$ As long as $ce{Pb}$, $ce{PbO2}$, and $ce{PbSO4}$ are available at the electrodes, the equilibrium cell voltage depends only on the acid concentration (that''s why equilibtrium cell