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All sodium-ion batteries (often also called salt batteries or salt accumulators) share a basic principle: they use sodium ions that move back and forth between the electrodes to store or release electrical energy.
Sodium-ion batteries are rapidly emerging as a promising solution for cost-effective energy storage. What Are Sodium-Ion Batteries? Sodium-ion batteries (SIBs) represent a significant shift in energy storage technology. Unlike Lithium-ion batteries, which rely on scarce lithium, SIBs use abundant sodium for the cathode material.
Sodium-ion batteries are a cost-effective alternative to lithium-ion batteries for energy storage. Advances in cathode and anode materials enhance SIBs' stability and performance. SIBs show promise for grid storage, renewable integration, and large-scale applications.
Table 6. Challenges and Limitations of Sodium-Ion Batteries. Sodium-ion batteries have less energy density in comparison with lithium-ion batteries, primarily due to the higher atomic mass and larger ionic radius of sodium. This affects the overall capacity and energy output of the batteries.
According to BloombergNEF, by 2030, sodium-ion batteries could account for 23% of the stationary storage market, which would translate into more than 50 GWh. But that forecast could be exceeded if technology improvements accelerate and manufacturing advances are made using similar or the same equipment as for lithium batteries.
The increasing demand for energy storage solutions drives the development of sodium ion technology. Additionally, the limited availability of lithium resources and rising prices contribute to the interest in sodium ion batteries. Recent studies show that sodium ion batteries can deliver energy densities comparable to those of lithium-ion batteries.
Sodium-ion batteries with aqueous electrolytes, often also referred to as saltwater batteries, represent a particularly innovative category in the world of energy storage systems and can be assigned to the category of redox-flow batteries.
Technology and its advancement has led to an increase in demand for electrical energy storage devices (ESDs) that find wide range of applications, from powering small electronic gadgets such as smart.
Lithium–sulfur (Li–S) batteries, which rely on the reversible redox reactions between lithium and sulfur, appears to be a promising energy storage system to take over from the conventional lithium-ion batteries for next-generation energy storage owing to their overwhelming energy density compared to the existing lithium-ion batteries today.
Lithium-ion sulfur batteries as a new energy storage system with high capacity and enhanced safety have been emphasized, and their development has been summarized in this review.
What is a lithium-sulfur battery? Unlike traditional lithium-ion batteries, Li-S batteries are electrochemical energy storage devices employing elemental sulfur as the cathode material and metallic lithium as the anode.
The Lithium-Sulfur Battery (LiSB) is one of the alternatives receiving attention as they offer a solution for next-generation energy storage systems because of their high specific capacity (1675 mAh/g), high energy density (2600 Wh/kg) and abundance of sulfur in nature.
The lithium-ion sulfur batteries not only maintain the advantage of high energy density because of the high capacities of sulfur and lithium sulfide, but also exhibit the improved safety of the batteries due to a non-lithium-metal in the anode.
The environmental advantages of lithium-sulfur batteries are substantial: These sustainability benefits align with global efforts to reduce the environmental footprint of energy storage technologies while meeting growing demand for batteries across multiple sectors.
In 2024, the spotlight is on new EV battery technology, with sodium-ion batteries leading the charge. This innovation offers remarkable advantages over the traditional lithium-ion options.
By combining anode materials used in conventional batteries with cathodes from supercapacitors — batteries that can store and deliver energy at very high rates –– the scientists created a new type of sodium-ion battery that offers both high capacity and rapid-charging capabilities.
Sodium batteries have a lower incidence of battery fires than conventional lithium batteries. The official energy density of the new sodium-ion battery has not been reported — however, CATL said it aims to exceed 200Wh/kg. Although the battery should launch in 2025, mass production is unlikely until 2027.
But sodium-ion batteries have some disadvantages. The big one is low energy density compared to lithium-ion. As a result, an EV running on a sodium-ion battery will go fewer miles per charge than a lithium-ion battery of the same size. “That is just what nature has given us,” Srinivasan said.
A typical sodium-ion battery has an energy density of about 150 watt-hours per kilogram at the cell level, he said. Lithium-ion batteries can range from about 180 to nearly 300 watt-hours per kilogram. I asked Srinivasan what he makes of CATL's claim of a sodium-ion battery with 200 watt-hours per kilogram.
And crucially, sodium-based batteries have recently been cramming more energy into a smaller package. In 2022, the energy density of sodium-ion batteries was right around where some lower-end lithium-ion batteries were a decade ago—when early commercial EVs like the Tesla Roadster had already hit the road.
CATL is not the only battery manufacturer developing sodium-ion batteries. In January, its rival BYD, the second-largest battery manufacturer in the world started construction of a sodium-ion factory with an annual production capacity of 30 GWh.
Researchers from the Technical University of Munich (TUM) and RWTH Aachen University in Germany have compared the electrical performance of high-energy sodium-ion batteries (SIBs) to that of a state-of-the-art high-energy lithium-ion battery (LIBs) with a lithium-iron-phosphate (LFP) cathode and have found that the state-of-charge and temperature have a higher influence on the pulse resistance and the impedance of the SIBs than the LIBs.
Therefore, future research on sodium iron phosphate must be a breakthrough in the synthesis method, in order to make it expected to be used on a large scale in sodium ion energy storage batteries.
Let's explore the many reasons that lithium iron phosphate batteries are the future of solar energy storage. Battery Life. Lithium iron phosphate batteries have a lifecycle two to four times longer than lithium-ion. This is in part because the lithium iron phosphate option is more stable at high temperatures, so they are resilient to over charging.
Lithium ion batteries have become a go-to option in on-grid solar power backup systems, and it's easy to understand why. However, as technology has advanced, a new winner in the race for energy storage solutions has emerged: lithium iron phosphate batteries (LiFePO4).
However, as technology has advanced, a new winner in the race for energy storage solutions has emerged: lithium iron phosphate batteries (LiFePO4). Lithium iron phosphate use similar chemistry to lithium-ion, with iron as the cathode material, and they have a number of advantages over their lithium-ion counterparts.
When needed, they can also discharge at a higher rate than lithium-ion batteries. This means that when the power goes down in a grid-tied solar setup and multiple appliances come online all at once, lithium iron phosphate backup batteries will handle the load without complications.
Additionally, lithium iron phosphate batteries can be stored for longer periods of time without degrading. The longer life cycle helps in solar power setups in particular, where installation is costly and replacing batteries disrupts the entire electrical system of the building.
Scientists at the US Department of Energy's Argonne National Laboratory have achieved an important advancement in making sodium-ion batteries more effective.
Researchers have developed a new type of material for sodium-ion batteries that could pave the way for a more sustainable and affordable energy future. (Representational image) University of Houston / Just_Super Researchers have developed a new type of material that could make sodium batteries more efficient.
One example is batteries based on sodium. Until a year ago, it was mostly lithium; now we know that sodium can play a role.” Northvolt's current sodium-ion batteries are designed for use in energy storage, but subsequent generations with higher energy density could eventually be used in electric vehicles.
CATL's first-generation sodium-ion battery. Credit: CATL Sodium-ion batteries for electric vehicles and energy storage are moving toward the mainstream. Wider use of these batteries could lead to lower costs, less fire risk, and less need for lithium, cobalt, and nickel.
Northvolt said on Tuesday that it had now validated a sodium-ion battery at the critical level of 160 watt hours per kilogramme, an energy density close to that of the type of lithium batteries typically used in energy storage.
Most of the push by battery companies to build sodium-ion systems is happening in China, but some of it is happening in other markets, including a plan by California-based Natron Energy to open its first large plant in Rocky Mount, North Carolina.
“Sodium-ion batteries could be cheaper and easier to produce, helping reduce reliance on lithium and making battery technology more accessible worldwide.” The researchers also created a battery prototype using the new material, NaxV2 (PO4)3, demonstrating significant energy storage improvements.
There are several options that can be used in to help mitigate the risk presented by lithium-ion battery charging, they include:Place the battery in an appropriately located fire compartment with access for maintenance and repair. Environmentally controlled environments, to prevent overheating of the space. Provide battery thermal management devices that automatically cut charging if issues detected.
Over the past four years, insurance companies have changed the status of Lithium-ion batteries and the devices which contain them, from being an emerging fire risk to a recognised risk, therefore those responsible for fire safety in workplaces and public spaces need a much better understanding of this risk, and how best to mitigate it.
There are several options that can be used in to help mitigate the risk presented by lithium-ion battery charging, they include: Place the battery in an appropriately located fire compartment with access for maintenance and repair. Environmentally controlled environments, to prevent overheating of the space. Fire Detection. Fire Suppression.
With the advantages of high energy density, short response time and low economic cost, utility-scale lithium-ion battery energy storage systems are built and installed around the world. However, due to the thermal runaway characteristics of lithium-ion batteries, much more attention is attracted to the fire safety of battery energy storage systems.
A survey of more than 500 organisations carried out between September 2023 and February 2024 revealed that 71 per cent of respondents had not updated their fire risk assessments to cover the risk of Lithium-ion battery fires, with just 15 per cent having done so and a further 14 per cent unsure.
This guide focusses on fire hazards and good-practice risk control measures for the charging of EVs using lithium-ion batteries, driven on highways, (i.e. cars, motorcycles, bicycles, lorries, coaches/buses, etc.) Lithium-ion batteries are the predominant type of rechargeable battery used in EVs.
Specific risk control measures should be determined through site, task and activity risk assessments, with the handling of and work on batteries clearly changing the risk profile. Considerations include: Segregation of charging and any areas where work on or handling of lithium-ion batteries is undertaken.
Below is a detailed explanation of the primary technical parameters of lithium batteries, along with additional related knowledge, to assist you in better applying and managing energy storage systems.
Learn about the key technical parameters of lithium batteries, including capacity, voltage, discharge rate, and safety, to optimize performance and enhance the reliability of energy storage systems. Lithium batteries play a crucial role in energy storage systems, providing stable and reliable energy for the entire system.
Lithium batteries play a crucial role in energy storage systems, providing stable and reliable energy for the entire system. Understanding the key technical parameters of lithium batteries not only helps us grasp their performance characteristics but also enhances the overall efficiency of energy storage systems.
Specific capacity, energy density, power density, efficiency, and charge/discharge times are determined, with specific C-rates correlating to the inspection time. The test scheme must specify the working voltage window, C-rate, weight, and thickness of electrodes to accurately determine the lifespan of the LIBs. 3.4.2.
Energy density is often a more relevant indicator than capacity in practical applications. Current lithium-ion battery technology achieves energy densities of approximately 100 to 200 Wh/kg. This level is relatively low and poses challenges in various applications, particularly in electric vehicles where both weight and volume are restricted.
LIBs are prominent energy storage devices to meet the growing energy demands of the modern era. They offer high specific capacity, energy density, thermal stability, and long calendar life compared to other types of batteries. LIBs are used in a diverse range of applications, from powering household appliances to supporting electric vehicles.
Battery storage is a technology that enables power system operators and utilities to store energy for later use.
A lead-acid battery consists of two lead plates separated by a liquid or gel containing sulfuric acid in water. The battery is rechargeable, with charging and discharging chemical reactions. When the battery is being used (discharged), electrons move from the negatively-charged lead plate to the positively-charged plate. The. When the battery is fully charged, the negative plate is lead, the electrolyte is concentrated sulfuric acid, and the positive plate is lead dioxide. If the battery is overcharged, electrolysis of water produces hydrogen gas. Calling sulfuric acid"battery acid" gives an indication of the acid concentration. There are, in fact, several different names for sulfuric acid that typically reflect its usage. 1. Concentration less than.
The battery acid is made of sulfuric acid (H2So4) diluted with purified water to get an overall concentration of around 29-32, a density of 1.25-1.28 kg/L, and a concentration of 4.2 mol/L. The pH value of electrolytes is about 0.8, so we need to take utmost care when handling battery acid. What Is Battery Acid?
Batteries contain acid because it's fundamental to the electrochemical reaction that takes place. Also referred to as battery electrolyte, battery acid is the medium that carries the electrical flow between positive and negative electrodes.
Car battery acid is around 35% sulfuric acid in water. Battery acid is a solution of sulfuric acid (H 2 SO 4) in water that serves as the conductive medium within batteries. It facilitates the exchange of ions between the battery's anode and cathode, allowing for energy storage and discharge.
Battery acid primarily refers to sulfuric acid, with the chemical formula H2SO4. Now, if we break that down, we get two hydrogen atoms, one sulfur atom, and four oxygen atoms working together in harmony to perform a critical role in the battery's operations. Think of it as the fuel that powers the entire battery system. Why Sulfuric Acid?
Battery acid (AKA sulfuric acid) is used in lead-acid batteries to help create and store electrical energy, which powers many devices and vehicles.
These batteries are highly corrosive, and react vigorously with the skin, causing burns and irritation. Battery acids have a high electrical conductivity. Usually, these acids are colorless. However, they can easily pick on impurities. The density of an acid battery is twice that of water.
Learn how raw materials like lead, sulfuric acid, and water come together to form these essential energy storage devices. From grid casting to battery formation, we explain each step in detail.
This document provides an overview of the lead acid battery manufacturing process. It discusses the key steps which include alloy production, grid casting, paste mixing and pasting, plate curing, and assembly. The alloy production process involves preparing mother alloy and KL-alloy from reclaimed lead using furnaces.
The lead battery is manufactured by using lead alloy ingots and lead oxide It comprises two chemically dissimilar leads based plates immersed in sulphuric acid solution. The positive plate is made up of lead dioxide PbO2 and the negative plate with pure lead.
A typical lead–acid battery contains a mixture with varying concentrations of water and acid. Sulfuric acid has a higher density than water, which causes the acid formed at the plates during charging to flow downward and collect at the bottom of the battery.
During the charging process, the cycle is reversed, that is, lead sulphate and water are converted to lead, lead oxide and electrolyte of sulphuric acid by an external charging source. This process is reversible, which means lead acid battery can be discharged or recharged many times.
The positive plate is made up of lead dioxide PbO2 and the negative plate with pure lead. The nominal electric potential between these two plates is 2 volts when these plates are immersed in dilute sulfuric acid. This potential is universal for all lead acid batteries.
In applications, a nominal 12V lead-acid battery is frequently created by connecting six single-cell lead-acid batteries in series. Additionally, it can be incorporated into 24V, 36V, and 48V batteries. Further, the lead acid manufacturing process has been discussed in detail. Lead Acid Battery Manufacturing Equipment Process 1.
The characteristics that define an EV battery performance are listed below: 1. Battery Capacity 2. C-Rate 3. Weight 4. Size 5. Power In order to understand them in detail, keep on reading the article. Battery capacity or Energy capacity is the ability of a battery to deliver a certain amount of power over a while. It is measured in kilowatt-hours (product of voltage and ampere-hours). It determines the energy available to the. A C-rating is used to define the rate at which a battery is fully charged or discharged. For instance, when the vehicle with an 85kWh battery is. The size of the battery of an electric vehicle has its own significance. Energy per volume is important to building a compact EV. Volumetric energy density means an amount of energy contained within a certain volume.It. The major part of an EV's weight comes from its battery. In general gross weight of a passenger EV, varies from 600kg to 2600kg with the battery weight varying from 100kg to 550kg.
[PDF Version]There are four main types of batteries that are used in electric vehicles, namely ultracapacitors / supercapacitors, lead-acid batteries, nickel-metal hydride batteries and lithium-ion batteries. In the ultracapacitor polarized liquid is stored between an electrode and an electrocyte.
Li-ion batteries are the preferred choice for modern electric cars due to their advanced rechargeable battery technology. However, they are relatively expensive to produce compared to other battery types. Nickel-Metal Hydride (NiMH) batteries gained commercial use in the late 1980s.
Beyond their 1500 charges and useful lifespan in a vehicle, electric vehicle batteries can be used for energy storage where performance isn't so important. For example, they can be used in motorhomes to store solar power, or as a backup for a power cut in our homes. Why are electric car batteries so expensive?
An electric vehicle battery is a rechargeable battery used to power the electric motors of a battery electric vehicle (BEV) or hybrid electric vehicle (HEV). They are typically lithium-ion batteries that are designed for high power-to-weight ratio and energy density.
NiMH batteries are known for their recyclability and are proven to be a suitable option for EVs, with an average battery life of 5-7 years. Lead-Acid batteries, formulated in 1859, are the oldest type of battery still in use. They are known for their low cost but have a shorter lifespan of around 3 years.
Nowadays, Lithium-ion batteries are by far the most widely used, this is due to them recharging quickly, being robust against temperature changes, and being able to maintain power for long durations, with bursts of very high power.
When the electrolyte in a lithium-ion battery freezes, it can cause the formation of lithium metal on the surface of the electrodes inside the battery. This can create a physical barrier that prevents the flow of ions between the. To maximize the efficiency of a lithium-ion battery at low temperatures, there are several strategies that can be used: 1.Keep the battery warm: One of the most effective ways to maintain. The runtime of a lithium-ion battery depends on several factors, including the capacity of the battery, the power requirements of the device.
Low-temperature batteries are designed to maintain performance in cold environments. In contrast, standard batteries often experience reduced capacity and efficiency in low temperatures.
Battery certification plays a crucial role in ensuring the safety and performance of battery products across various industries. In this guide, we'll break down the essential certifications you need to know, including the types of certifications, the costs involved, expected timeframes, and the standards that govern them.
Low-temperature batteries may sacrifice some capacity or energy density to maintain performance in cold environments. In contrast, standard batteries typically offer higher capacity and energy density under normal operating conditions. Standard batteries may perform better in moderate temperatures but struggle in colder climates.
The lowest temperature at which most batteries can operate without damage is typically around -20 °C to -40 °C (- 4°F to 40°F). However, this can vary depending on the type of battery and its chemistry. What is the low temperature for a LiPo battery? LiPo batteries perform best at temperatures above 0°C (32°F).
LiFePO4 batteries can generally operate safely down to around -20°C. Beyond this temperature, their performance may decline, potentially damaging them. The low temperature li-ion battery solves energy storage in extreme conditions. This article covers its definition, benefits, limitations, and key uses.
In Europe, lithium-ion batteries must meet CE Marking requirements for safety, health, and environmental standards. Additional certifications like IEC 62133 or UN38.3 may be needed for transport and use. What to consider when choosing a certification body?
In this article, we will examine a circuit that allows charging Li-ion cells connected in series while also balancing them during the charging process.
The following graph suggests the ideal charging procedure of a standard 3.7 V Li-Ion Cell, rated with 4.2 V as the full charge level. Stage#1: At the initial stage#1 we see that the battery voltage rises from 0.25 V to 4.0 V level in around one hour at 1 amp constant current charging rate. This is indicated by the BLUE line.
If the cells are protected and one cell charges faster than the other it's protection will cut it off and current will not flow the other battery in series. That is the function of battery management circuits. Lithium ion batteries are fully charged at 4.2V, and discharged at about 3 V.
Although Li-Ion batteries are vulnerable devices, these can be charged through simpler circuits if the charging rate does not cause significant warming of the battery., and if the user does not mind a slight delay in the charging period of the cell.
It is possible to charge the cells individually, but limit the current and don't exceed 4.2V, and monitor the battery temperature. Many lithium batteries have built in protection for overdischarge.
The charging also different than the lead-acid batteries. The 3.9v Lithium-ion batteries need 4.2 v of charging voltage and 1A charging current. The charging time is about 2-3 hours. if the optimized charging is not done, the battery will be damaged or reduces the battery capacity.
You can also view the Lithium battery Charger PCB, how it will look after fabrication using the Photo View button in EasyEDA: After completing the design of this Lithium battery Charger PCB, you can order the PCB through JLCPCB.com. To order the PCB from JLCPCB, you need Gerber File.
This article will provide an in-depth look at the best practices for extinguishing a lithium battery fire, including the types of extinguishers to use, safety precautions, and post-fire procedures.
The following fire extinguishers are specifically designed for use on lithium-ion battery fires which are not the same as standard lithium batteries (use a Class D L2 Powder Extinguisher on standard lithium battery fires).
Our lithium battery fire extinguishers are specially designed to put out such fires. Lith-ex fire extinguishers use a non-toxic and revolutionary extinguishing agent called AVD or Aqueous Vermiculite Dispersion, which is deployed as a mist to create a film over surfaces.
Application: Aim the extinguisher at the base of the fire, and apply the powder evenly to cover the burning material. Lithium-ion battery fires can be effectively managed with standard dry chemical or ABC fire extinguishers. These extinguishers use a dry chemical agent to interrupt the chemical reaction of the fire. Key Points:
Proper use of a lithium-ion fire extinguisher, following the manufacturer's instructions and ensuring it is rated specifically for lithium-ion battery fires, is essential for effectively managing these dangerous fires. Why Should You Also Have a Lithium-Ion Fire Blanket?
While CO2 extinguishers are effective for many types of fires, they are not suitable for lithium battery fires. They do not cool the battery sufficiently, and the fire may re-ignite once the CO2 dissipates. If it is safe to do so, disconnect the battery or power source to cut off the supply of electricity.
Foam extinguishers are also ineffective and unsafe for lithium battery fires. While CO2 extinguishers are effective for many types of fires, they are not suitable for lithium battery fires. They do not cool the battery sufficiently, and the fire may re-ignite once the CO2 dissipates.
Sealed lead acid batteries may be charged by using any of the following charging techniques: 1. Constant Voltage 2. Constant Current 3. Taper Current 4. Two Step Constant Voltage To obtain maximum battery ser. During constant voltage or taper charging, the battery's current acceptance decreases as voltage and state of charge increase. The battery is fully charged once the current stabilize. Selecting the appropriate charging method for your sealed lead acid battery depends on the intended u. Constant voltage charging is the best method to charge sealed lead acid batteries. Depending on the application, batteries may be charged either on a continuous or no. Constant current charging is suited for applications where discharged ampere-hours of the preceding discharge cycle are known. Charge time and charge quantity can easily be cal.
The lead-acid battery mainly uses two types of charging methods namely the constant voltage charging and constant current charging. It is the most common method of charging the lead acid battery. It reduces the charging time and increases the capacity up to 20%. But this method reduces the efficiency by approximately 10%.
Just multiply the voltages by 2 for 24V or 4 for 48V batteries. The only way to get an accurate reading of a lead acid battery's state of charge from voltage is to measure its open circuit voltage. This means the battery must be disconnected from all loads and chargers and allowed to rest for several hours until its voltage stabilizes.
The optimal charging voltage for 48V flooded lead acid batteries is typically around 58V to 62V at the start of charging. Sealed batteries may need slightly higher voltages. Refer to the battery specifications. How Can I Revive a Dead Lead Acid Battery?
Customers often ask us about the ideal charging current for recharging our AGM sealed lead acid batteries. We have the answer: 25% of the battery capacity. The battery capacity is indicated by Ah (Ampere Hour). For example: In a 12V 45Ah Sealed Lead Acid Battery, the capacity is 45 Ah.
For example: In a 12V 45Ah Sealed Lead Acid Battery, the capacity is 45 Ah. So, the charging current should be no more than 11.25 Amps (to prevent thermal runaway and battery expiration). Importantly, if you have other equipment connected to the battery during chargning, it also needs to be powered, so you need to add that to your calculations.
In this method the charging current is high in the beginning when a battery is in discharged condition, and it gradually drops off as the battery picks up charge resulting in increased back emf. Charging at constant voltage may be carried out only when the batteries have the same voltage, for example, 6 or 12 or 24 V.
The end result may include (a) physical expansion of plates, (b) increased internal resistance, (c) reduced power capability, and (d) eventual battery failure.
If the water level gets too low, the plates will start to corrode and the battery will eventually fail. If you have a lead-acid battery, it is important to keep it full of water. If the water level gets too low, the battery are ruined. What Happens If Lead Acid Battery Runs Out of Water?
When a lead acid battery is drained of its acid, the wet moist negative electrodes come in contact with atmospheric oxygen, triggering an exothermic reaction that releases heat and discharges the negative plates (electrodes), oxidizing the sponge lead to lead oxide.
A lead acid battery is a type of rechargeable battery that has positive and negative plates fully immersed in electrolyte, which is dilute sulphuric acid.
A lead acid battery, including flooded electrolyte types, should not have its acid completely removed once it has been filled and charged. It is important not to remove the acid. A lead acid battery consists of several major components, including the positive electrode, negative electrode, sulphuric acid, separators, and tubular bags.
If you have a lead acid battery to charge it, it's important to keep it filled with water. If the battery runs out of water, it will no longer be able to generate power. The lead plates in the battery will start to corrode, and the battery will eventually fail. Will Tap Water Ruin a Battery?
Flooded electrolyte lead acid batteries do not cause thermal runaway because the electrolyte, which acts as a coolant in these batteries, helps prevent such an occurrence. Designers of flooded electrolyte lead acid batteries do not face the thermal runaway problems that are common in sealed maintenance free (SMF) or valve regulated lead acid (VRLA) batteries.