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A stand-alone and removable lithium ion cell that is used without the necessary safety protection features like those found in multi-cell battery packs or cells intended to be used as “single cell lithium ion batteries” present a unique and significant safety risk for all involved in their handling.
Though cylindrical batteries often incorporate safety devices, the safety of the battery also depends on its design and manufacturing processes. This study conducts a design and process failure mode and effect analysis (DFMEA and PFMEA) for the design and manufacturing of cylindrical lithium-ion batteries, with a focus on battery safety. 1.
Major safety concerns for lithium-ion batteries are thermal runaway and explosion. Thermal runaway is a phenomenon where exothermic reactions occur within the cell, leading to a rapid temperature increase, potentially causing the cell to catch fire .
Single lithium-ion batteries (also referred to as cells) have an operating voltage (V) that ranges from 3.6–4.2V. Lithium ions move from the anode to the cathode during discharge. The ions reverse direction during charging. The lithiated metal oxide or phosphate coating on the cathode defines the “chemistry” of the battery.
Cylindrical batteries are composed of a rolled-up assembly called a jelly roll, which includes anode, cathode, and separator sheets tightly wound together and connected with electrical tabs. A schematic of a cylindrical lithium-ion battery is shown in Figure 2. Figure 2. Cylindrical battery structure.
Stable LIB operation under normal conditions significantly limits battery damage in the event of an accident. As a result of all these measures, current LIBs are much safer than previous generations, though additional developments are still needed to improve battery safety even further.
Experts recommend to put the cells in storage mode after every run, this will help the battery to lengthen the usable life span. Remove the lithium-ion battery from a device before storing it. It is a good practice to use a lithium-ion battery fireproof safety bag or other fireproof container when storing batteries.
The best way to fix it is using an overvoltage-protected charger, charge your bare lithium battery directly; do not charge it using a universal charger. It has the potential to be quite hazardous.
Unfortunately, when your Lithium Iron battery refuses to charge, there could be a variety of reasons behind the problem. The issues might stem from a damaged battery or external factors unrelated to the lithium battery itself. It may require some trial and error as well as battery troubleshooting to uncover the underlying cause.
Lithium batteries degrade over time, losing their ability to hold a charge. If your battery is old or you've used it extensively, it may be reaching the end of its lifespan. Part 2. How do you fix a lithium-ion battery that won't charge?
If your lithium battery won't charge, try resetting the battery. Remove the battery from the device and leave it out for 5-10 minutes. Then, place it back in the device and attempt charging again. This can sometimes “reset” the battery and resolve minor issues that may be preventing it from charging.
Ensure the ambient temperature is above 41°F. - All battery terminal connections have been removed. - Use a charger with lithium battery activation to charge the battery to above 12.4V/24.8V. Negative: Confirm that the battery is not in undervoltage protection. Please proceed to the remaining steps.
Try using a different charger and cable to see if the issue persists. Check for visible damage to the charging cable, such as fraying or exposed wires. Test your charger with another device to ensure it's working properly. If your lithium battery won't charge, try resetting the battery.
Whilst it's not unsafe to fully discharge a lithium battery, a device like the Smart Battery Protect will ensure you never get into the situation where your charger cannot wake up your BMS (if your charger doesn't have a 'wake-up' facility).
The 7 Largest Lithium Battery Companies In The World, And What They Do1. SK On A subsidiary of the South Korean conglomerate SK Innovation, SK On is a leading lithium-ion battery manufacturer. CATL stands for Contemporary Amperex Technology Co. Limited, a Chinese company headquartered in Ningde, Fujian.
China is the undisputed leader in battery manufacturing, dominating the global production of essential battery materials such as lithium, cobalt, and nickel. Chinese companies supply 80% of the world's battery cells and control nearly 60% of the EV battery market. 13. Amperex Technology Limited (ATL) 12. Envision AESC 11. Gotion High-tech 10.
As this technology becomes more integral to our daily lives, battery manufacturing is pivotal to global energy solutions, the market for lithium-ion battery manufacturers has expanded, with companies competing to produce the most efficient, durable, and environmentally friendly solutions.
According to SME Research, CATL is the world's largest EV battery manufacturer, with 37.7% of the market share. Plus, it is the only battery supplier with a market share of over 30%. CATL has 6 R&D facilities, five in China and one in Germany. In 2023, they spent about $2.59 billion in R&D, an 18.35% increase from the previous year.
In 1999, LG Chem made Korea's first lithium-ion battery. Later, in the 2000s, it supplied batteries for the General Motors Volt. After that, the company became a key supplier for many global car brands, such as Ford, Chrysler, Audi, Renault, Volvo, Jaguar, Porsche, Tesla, and SAIC Motor.
Panasonic Energy Co., Ltd., with a rich history and strong market presence, is a key player in the global lithium-ion battery market. Its commitment to advancing technology and sustainable solutions marks its significant industry presence.
It is the largest EV battery producer globally, manufacturing 96.7 GWh in one year—a 167.5% increase. CATL works with major car makers worldwide, creating batteries for all kinds of EVs, from small cars to trucks. They are also known for innovation, like developing safer, cobalt-free LFP batteries that are better for the environment.
Lithium-ion batteries are currently the most popular choice for PV storage systems. They offer high energy density, longer lifespan, and better efficiency.
Lithium-ion batteries, with their superior performance characteristics, have emerged as the cornerstone technology for solar energy storage. This article delves into the science behind lithium-ion batteries, their advantages over traditional storage solutions, and key considerations for optimizing their performance.
Innovations in battery technology, such as improved thermal management and advanced battery management systems (BMS), have enhanced their performance and safety, making them even more attractive for PV applications. The predominance of lithium-ion batteries in PV systems translates to more efficient and reliable energy storage solutions.
PV systems typically use lead-acid, lithium-ion, and flow batteries, each offering distinct advantages depending on the specific energy storage requirements. Photovoltaic systems rely on batteries to store the energy generated by solar panels, ensuring a consistent power supply even when the sun isn't shining.
Lithium-ion batteries are the most used type in PV systems due to their superior energy density, longer lifespan, and higher efficiency compared to other battery types. When it comes to energy storage in photovoltaic systems, lithium-ion batteries have emerged as the dominant technology.
The solar energy market has witnessed a substantial increase in the adoption of lithium-ion batteries. Innovations in battery technology, such as improved thermal management and advanced battery management systems (BMS), have enhanced their performance and safety, making them even more attractive for PV applications.
Lithium-ion battery systems are highly scalable, allowing for easy expansion as energy storage needs grow. Whether it's a small home installation or a large commercial setup, lithium-ion batteries can be configured to meet varying energy demands. The versatility of lithium-ion batteries makes them suitable for a wide range of solar applications:
While BESS technology is designed to bolster grid reliability, lithium battery fires at some installations have raised legitimate safety concerns in many communities.
Conclusions Large-scale, commercial development of lithium-ion battery energy storage still faces the challenge of a major safety accident in which the battery thermal runaway burns or even explodes. The development of advanced and effective safety prevention and control technologies is an important means to ensure their safe operation.
Their ability to store large amounts of energy in a compact and efficient form has made them the go-to technology for Lithium-ion Battery Energy Storage Systems (BESS). However, this rapid adoption has also uncovered significant safety concerns, particularly fire and explosion hazards.
Introduction to Lithium-ion Battery Energy Storage Systems (BESS) Lithium-ion batteries are highly efficient due to their high energy density, long cycle life, and ability to recharge quickly.
Among these, lithium-ion batteries (LIBs) energy storage technology, as one of the most mainstream energy storage technologies, has the advantages of mature technology, high energy density and excellent cycle stability compared with other energy storage technologies [11, 12].
Such as the thermal-electrical-chemical abuses led to safety accidents is increasing, which is a serious challenge for large-scale commercial application of electrochemical energy storage power stations (EESS).
As the most fundamental energy storage unit of the battery storage system, the battery safety performance is an essential condition for guaranteeing the reliable operation of the energy storage power plant. LIBs are usually composed of four basic materials: cathode, anode, diaphragm and electrolyte .
The lithium iron phosphate battery (LiFePO 4 battery) or LFP battery (lithium ferrophosphate) is a type of using (LiFePO 4) as the material, and a with a metallic backing as the. Because of their low cost, high safety, low toxicity, long cycle life and other factors, LFP batteries are finding a number o.
China is the largest producer and consumer of lithium iron phosphate materials. Its dominance in the battery manufacturing sector, coupled with government policies promoting renewable energy and EV adoption, has cemented its position as the global leader in LFP production.
Current collectors are vital in lithium iron phosphate batteries; they facilitate efficient current conduction and profoundly affect the overall performance of the battery. In the lithium iron phosphate battery system, copper and aluminum foils are used as collector materials for the negative and positive electrodes, respectively.
Below are some common lithium iron phosphate recycling strategies and methods: (1) Physical method: Through disassembling, crushing, sorting, and other physical means, different components in the battery are separated to obtain recyclable materials, such as copper, aluminum, diaphragm, and so on.
Lithium iron phosphate is an important cathode material for lithium-ion batteries. Due to its high theoretical specific capacity, low manufacturing cost, good cycle performance, and environmental friendliness, it has become a hot topic in the current research of cathode materials for power batteries.
Resource sharing is another important aspect of the lithium iron phosphate battery circular economy. Establishing a battery sharing platform to promote the sharing and reuse of batteries can improve the utilization rate of batteries and reduce the waste of resources.
Image used courtesy of USDA Forest Service Iron phosphate is a black, water-insoluble chemical compound with the formula LiFePO 4. Compared with lithium-ion batteries, LFP batteries have several advantages. They are less expensive to produce, have a longer cycle life, and are more thermally stable.
The current costs of sodium and lithium-ion batteries show that lithium-ion batteries are generally more expensive, while sodium batteries present a promising, cheaper alternative.
Sodium is more than 500 times more abundant than lithium, which is available in a few countries. Sodium-ion battery charges faster than lithium-ion variants and have a three times higher lifecycle. However, sodium-ion batteries lack of a well-established raw material supply chain and the technology is still in early stages of development.
Raw Material Abundance: Sodium is one of the most common elements on Earth, making sodium-ion batteries less expensive to produce. In contrast, lithium is scarcer and more costly, contributing to the higher price of lithium-ion batteries.
While there are some similarities between sodium- and lithium-ion battery cell designs, understanding how they differ can help determine the best choice for a given application. Sodium-ion battery cells, like lithium-ion, are comprised of positive and negative electrodes, a separator, and an electrolyte.
However, early sodium-ion batteries faced significant challenges, including lower energy density and shorter cycle life, which hindered their commercial viability. Despite these setbacks, interest in sodium-ion technology persisted due to the abundance and low cost of sodium compared to lithium.
It's unlikely that sodium-ion batteries will completely replace lithium-ion batteries. Instead, they are expected to complement them. Sodium-ion batteries could take over in niches where their specific advantages—such as lower cost, enhanced safety, and better environmental credentials—are more critical.
Batteries are compared using the proposed bottom-up assessment framework. The economic-ecological-efficiency analysis is conducted for batteries. The deep-decarbonization effectiveness of batteries is analyzed. Vanadium redox batteries outperform lithium-ion and sodium-ion batteries. Sodium-ion batteries have the shortest carbon payback period.
Most electric vehicles humming along Australian roads are packed with lithium-ion batteries. They're the same powerhouses that fuel our smartphones and laptops – celebrated for their ability to store heaps of energy in a small space. The reality is lithium-ion batteries in electric vehicles are very safe. In fact, from 2010. If a fire bursts out in an EV or battery storage facility, the first instinct may be to grab the nearest hose. However, getting too close to the fire could spell disaster as you may be injured by jet. Although EV fires are very rare, if you do own an EV (or plan to in the future), there are a few steps you can take to tip the scale in your favour. First, get to know your EV inside and out.
Exposure to lithium-ion battery smoke can adversely affect human health. Lithium-ion batteries contain various chemicals, including lithium, cobalt, and solvents. When these batteries experience damage, overheating, or malfunction, they can release toxic smoke.
Cathode Decomposition: At high temperatures, the cathode material (for example LiCoO₂) is decomposing and releasing oxygen which is driving the fire. To be very safe in the use of batteries and prevent such fires, there is a need to understand what led to such fires. Here are top 8 reasons why lithium-ion batteries catch fires. 1. Overcharging
Understanding what chemicals are released when a lithium-ion battery emits smoke requires examining the specific substances that are generated during thermal runaway and combustion. Hydrogen fluoride is a toxic gas released during the thermal decomposition of lithium-ion batteries.
When a lithium-ion battery fire breaks out, the damage can be extensive. These fires are not only intense, they are also long-lasting and potentially toxic. What causes these fires? Most electric vehicles humming along Australian roads are packed with lithium-ion batteries.
Over the past four years, insurance companies have changed the status of Lithium-ion batteries and the devices which contain them, from being an emerging fire risk to a recognised risk, therefore those responsible for fire safety in workplaces and public spaces need a much better understanding of this risk, and how best to mitigate it.
Individuals most at risk from lithium-ion battery smoke include firefighters, emergency responders, and nearby residents. Firefighters face exposure during firefighting operations. Emergency responders may inhale toxic fumes while assisting victims.
The lithium iron phosphate battery (LiFePO 4 battery) or LFP battery (lithium ferrophosphate) is a type of using (LiFePO 4) as the material, and a with a metallic backing as the. Because of their low cost, high safety, low toxicity, long cycle life and other factors, LFP batteries are finding a number o.
Lithium iron phosphate modules, each 700 Ah, 3.25 V. Two modules are wired in parallel to create a single 3.25 V 1400 Ah battery pack with a capacity of 4.55 kWh. Volumetric energy density = 220 Wh / L (790 kJ/L) Gravimetric energy density > 90 Wh/kg (> 320 J/g). Up to 160 Wh/kg (580 J/g).
Multiple lithium iron phosphate modules are wired in series and parallel to create a 2800 Ah 52 V battery module. Total battery capacity is 145.6 kWh. Note the large, solid tinned copper busbar connecting the modules together. This busbar is rated for 700 amps DC to accommodate the high currents generated in this 48 volt DC system.
The most notable difference between lithium iron phosphate and lead acid is the fact that the lithium battery capacity shows only a small dependence on the discharge rate. With very high discharge rates, for instance 0.8C, the capacity of the lead acid battery is only 60% of the rated capacity.
The LFP battery uses a lithium-ion-derived chemistry and shares many advantages and disadvantages with other lithium-ion battery chemistries. However, there are significant differences. Iron and phosphates are very common in the Earth's crust. LFP contains neither nickel nor cobalt, both of which are supply-constrained and expensive.
LiFePO 4 batteries are comparable to sealed lead acid batteries and are often being touted as a drop-in replacement for lead acid applications. The most notable difference between lithium iron phosphate and lead acid is the fact that the lithium battery capacity shows only a small dependence on the discharge rate.
The effects of temperature on lithium iron phosphate batteries can be divided into the effects of high temperature and low temperature. Generally, LFP chemistry batteries are less susceptible to thermal runaway reactions like those that occur in lithium cobalt batteries; LFP batteries exhibit better performance at an elevated temperature.
Batteries should be stored in non-flammable containers, such as concrete, metal or packaging designed specifically for storing lithium batteries, large enough that the batteries are not touching each other.
The Lithium-ion Batteries in Containers Guidelines seek to prevent the increasing risks that the transport of lithium-ion batteries by sea creates, providing suggestions for identifying such risks and thereby helping to ensure a safer supply chain in the future.
* The outer packaging must be a strong rigid outer package that is capable of withstanding a 1.2 meter drop test without damage to the cells or batteries, without shifting that would allow battery-to-battery contact, and without release of the contents of the package. • For packages with lithium cells or batteries contained in equipment:
In general lithium-ion batteries should always be removed from the devices they power and stored at 60-70% of the pack's capacity. If a battery will go unused for three more days, it should be stored in a cabinet or larger store. Once disconnected, storing lithium-ion batteries follows similar principles as the correct storage of chemicals.
These regulations depend on the size (watt hour) of the battery and condition of the battery (damaged vs. non-damaged). Storing lithium batteries presents unique challenges because there are both national regulations and unique ordinances to follow, while some countries don't have specific rules for them.
For the purposes of this document, the ways to describe and configure packages of lithium cells and batteries, including smaller cells and batteries, are divided between ten distinct, standalone shipping guides. The shipping guides are numbered Guide 01 - Guide 10.
• Except for vehicles transported by highway, rail, or vessel with prototype or low production lithium batteries securely installed, each lithium battery must be of a type that has successfully passed the UN 38.3 tests, unless approved by PHMSA's Associate Administrator.
To extinguish a lithium-ion battery fire, use a Class D fire extinguisher or cover it with sand if safe. Avoid using water as it can exacerbate the fire.
Lithium-ion battery fires are typically caused by thermal runaway, where internal temperatures rise uncontrollably. Lithium-ion battery fires can be prevented through careful handling, proper storage and regular monitoring. Fire extinguishers explicitly designed for lithium-ion battery fires are the best to use.
Controlling a lithium-ion battery fire requires a specific approach due to the unique chemical reactions involved. Here's how such fires can be managed: Evacuate the Area: Immediately evacuate everyone from the area where the battery fire has occurred.
The batteries contain liquid electrolytes that provide a conductive pathway, hence the Class B classification. To extinguish a lithium-ion battery fire, use a standard ABC or dry chemical fire extinguisher. Clean agent fire suppression systems are particularly well-suited for addressing lithium-ion battery fires.
Flammable and Toxic Gasses: During a fire, lithium-ion batteries can release highly reactive and toxic gasses. Reignition: Even after being extinguished, lithium-ion battery fires can reignite due to residual heat in the internal battery components. Lithium-ion batteries power a wide range of devices, including:
Do Not Touch Residue: After the fire has been extinguished, avoid touching any residue barehanded. Lithium battery fires can leave behind toxic compounds. Dispose of the Battery Safely: Contact local hazardous waste disposal services to handle the burnt battery properly. Never throw it in regular trash.
In the case of fires involving large arrays of lithium-ion battery cells, like those used in electric vehicles, lithium-ion battery fires are normally only controlled and extinguished when the fire and rescue service deliver a large amount of water to the burning materials for a significant amount of time.
Determine the Number of Cells in a Lithium-Ion Battery Pack for Optimal Runtime1. Divide the battery voltage rating by the nominal voltage rating to get cells in series.
For instance, LiTime allows for a maximum of four 12V lithium batteries to be connected in series, resulting in a 48-volt system. It's always important to consult the battery manufacturer to ensure that you stay within their recommended limits for series connections.
To get the voltage of batteries in series you have to sum the voltage of each cell in the serie. To get the current in output of several batteries in parallel you have to sum the current of each branch .
Connecting lithium-ion batteries in parallel or in series is not as straightforward as a simple series-parallel connection of circuits. To ensure the safety of both the batteries and the individual handling them, several important factors should be taken into consideration.
It depends on your specific needs. Two 100Ah batteries in parallel would provide more flexibility and redundancy, but a single 200Ah battery might be simpler to manage. Can we connect a 150Ah battery with a 200Ah battery in series? Connecting batteries in series requires them to have the same capacity.
In series, connect batteries' positive to negative terminals to increase voltage. In parallel, connect positive to positive and negative to negative to increase capacity. Series adds voltage, parallel adds capacity. Combining both allows customizing voltage and capacity, useful for various applications.
In series: Add the voltages of the batteries while keeping the same capacity (Ah). In parallel: Keep the voltage the same and add the capacities (Ah) of the batteries. What is the formula for calculating battery size?
LFP has two shortcomings: low conductivity (high overpotential) and low lithium diffusion constant, both of which limit the charge/discharge rate. Adding conducting particles in delithiated FePO 4 raises its electron conductivity. For example, adding conducting particles with good diffusion capability like graphite and carbon to LiMPO 4 powders significantly improves conductivity between particles, increases the efficiency of LiMPO 4 and raises its reversible capacity up to 9. The lithium iron phosphate battery (LiFePO 4 battery) or LFP battery (lithium ferrophosphate) is a type of using (LiFePO 4) as the material, and a with a metallic backing as the. Because of their low cost, high safety, low toxicity, long cycle life and other factors, LFP batteries are finding a number o.
These batteries have found applications in electric vehicles, renewable energy storage, portable electronics, and more, thanks to their unique combination of performance and safety The chemical formula for a Lithium Iron Phosphate battery is: LiFePO4.
Lithium Iron Phosphate (LiFePO4 or LFP) batteries are a type of rechargeable lithium-ion battery known for their high energy density, long cycle life, and enhanced safety characteristics. Lithium Iron Phosphate (LiFePO4) batteries are a promising technology with a robust chemical structure, resulting in high safety standards and long cycle life.
Under low-temperature conditions, the performance of lithium iron phosphate batteries is extremely poor, and even nano-sizing and carbon coating cannot completely improve it. This is because the positive electrode material itself has weak electronic conductivity and is prone to polarization, which reduces the battery volume.
Lithium iron phosphate is an important cathode material for lithium-ion batteries. Due to its high theoretical specific capacity, low manufacturing cost, good cycle performance, and environmental friendliness, it has become a hot topic in the current research of cathode materials for power batteries.
The impact of lithium iron phosphate positive electrode material on battery performance is mainly reflected in cycle life, energy density, power density and low temperature characteristics. 1. Cycle life The stability and loss rate of positive electrode materials directly affect the cycle life of lithium batteries.
Lithium Iron Phosphate (LiFePO4) batteries are a promising technology with a robust chemical structure, resulting in high safety standards and long cycle life. Their cathodes and anodes work in harmony to facilitate the movement of lithium ions and electrons, allowing for efficient charge and discharge cycles.
Three different make standards on batteries: TC21 (), SC21 (other ) and TC35 (). Each group has published standards relating to the nomenclature of - IEC 60095 for lead-acid, IEC 61951-1 and 61951-2 for and batteries, IEC 61960 for, and IEC 60086-1 for primary batteries.
The numbers on a lithium battery provide important information about the battery's dimensions or capacity. For Cylindrical Batteries (e.g., 18650): The numbers refer to the battery's physical size. In “18650″: 18 = Diameter of the battery in millimeters (18mm). 65 = Length of the battery in millimeters (65mm). 0 = Cylindrical shape.
Battery codes typically consist of a series of letters and numbers, each providing distinct information about the battery. While there is no single standard for all battery types, certain conventions are commonly followed across different categories:
Battery codes also help in choosing a battery that offers the best performance for a given application. For instance, if you need a battery for a high-drain device, selecting a code that indicates a high-capacity lithium chemistry, such as 18650, would be ideal.
Battery codes are sometimes standardized by organizations such as the International Electrotechnical Commission (IEC) and the American National Standards Institute (ANSI). These bodies have established guidelines for labeling batteries, ensuring that codes are consistent and universally recognized.
Certain sizes, given by one or two digit numbers, represent standard size codes from previous editions of the standard. Sizes given as 4 or more digits indicate the diameter of the battery and the overall height. The numbers in the code correlate with the battery dimensions.
The complete nomenclature for the battery will fully specify the size, chemistry, terminal arrangements, and special characteristics of a battery. The same physically interchangeable cell size may have widely different characteristics; physical interchangeability is not the sole factor in substitution of batteries.
First of all, we should know that when two or more lithium iron phosphate batteries are connected in parallel, the current flowing through each battery cannot be exactly equal. For example, suppose you are using two 12V 100Ah batteries in parallel. When the battery system is connected to a 50A load, the load on each cell. Current imbalance between cells is caused by field installation variables. For example, differences in cell and battery manufacturing processes, differences in cell connection resistance,. Before connecting batteries in parallel, you may need to pay attention to the following matters. 1. Do not mix different brands and capacities of batteries Make sure the parallel-connected batteries match strictly internal resistance:. When connecting two or more batteries in parallel that are new and have the same capacity and voltage brand, the power pushed between the.
[PDF Version]First of all, we should know that when two or more lithium iron phosphate batteries are connected in parallel, the current flowing through each battery cannot be exactly equal. For example, suppose you are using two 12V 100Ah batteries in parallel. When the battery system is connected to a 50A load, the load on each cell cannot be exactly 25A.
If you have ever sought information about connecting Lithium Iron Phosphate (LiFePO4 or LFP) batteries in parallel for your application and been left confused by conflicting information, let me clear the buzz and explain why some sources allow us to connect LFP batteries in parallel and others do not recommend it at all.
For instance, if 4 100Ah batteries are connected in parallel, the overall capacity of the battery pack will be 400Ah. In contrast, series connection of LiFePO4 batteries does not increase the overall capacity of the battery pack; it only increases the voltage output.
You also want to make sure that you never short circuit that battery pack as it will have an incredible amount of power and can release that power really quickly. Putting the cells in parallel also lowers the internal resistance. Where did you read that 3 is the maximum for parallel for regular lithium ion?
Yes, you can connect 12V lithium batteries in parallel. When connected in parallel, the voltage remains the same (12V in this case), but the capacity (Ah) adds up. It's essential to make sure the batteries you're connecting have the same voltage level and ideally the same state of charge to prevent unwanted current flows between the batteries.
Make sure the parallel-connected batteries match strictly internal resistance: capacity, voltage, and brand are exactly the same, and you cannot mix old and new batteries. If batteries of different capacities are used together, current imbalance will occur between the two batteries, thus reducing the running time of the battery system.