The structural disorder, large grain boundaries, and significantly high defect density within polycrystalline perovskite solar cells (PC-PSCs) have raised the issue of their sustainability for an extended period. The. ••Single crystal based solar cells as the big new wave in perovskite photovoltaic t. After the discovery of perovskite-based materials by German mineralogist Gustav Rose in 1839, the applications of perovskite materials have been extensively explored because of their. Perovskite single crystals have several advantages over polycrystalline perovskites. Since 2015, single-crystal perovskites have been proven to possess unique properties. Various methods for synthesizing high-quality perovskite single crystals have been successfully demonstrated over the past few years. However, only a few of them are appropriate from. Single-crystal perovskite-based materials exhibit high stability and enhanced optoelectronic properties, rendering them suitable for photovoltaic applications. However, the per.
